Benzoquinonoid-bridged dinuclear actinide complexes
نویسندگان
چکیده
منابع مشابه
Dinuclear dialkoxo-bridged cyclopentadienylsiloxo titanium complexes.
The dinuclear dialkoxo-bridged complexes [(TiCl)(2)(mu-O(2)L)(mu-{(eta(5)-C(5)Me(4)SiMeO)(2)(mu-O)})] (O(2)L = 1,2-O(2)C(2)H(4), 1,2-O(2)C(6)H(4), 1,2-(OCH(2))(2)C(6)H(4), O(2)SiPh(2)) were obtained by reaction of [(TiCl(2))(2)(mu-{(eta(5)-C(5)Me(4)SiMeO)(2)(mu-O)})] () with the corresponding dilithium salt () or diol (, , ). Alkylation of and with ClRMg afforded [(TiR)(2)(mu-O(2)L)(mu-{(eta(5)...
متن کاملBent dinuclear platinum(II) halo-bridged carbonyl complexes.
Crystals of trans-Pt₂(μ-X)₂X₂(CO)₂ (X = Br, I) have been grown and their molecular and crystalline structures have been solved by X-ray diffraction methods. In both cases the dinuclear molecules are bent, with a bending angle of 164.6° and 156.5° for the bromide and the iodide, respectively. While the structure of the bromo-derivative is reported here for the first time, a modification of trans...
متن کاملSynthesis, Spectroscopy and Magnetism of Alkoxobridged Dinuclear Copper(II) Complexes with 2 Amino Picolines as the Ligands
The synthesis, spectroscopic and magnetic characterization of a series of new alkoxo-bridged binuclear copper (II) compounds are described. All complexes have the general formula [Cu (m-OR)(L)2]2(ClO4)2 · x H2O, in which m-OR = CH3O-, C2H5O- or C3H7O-<e...
متن کاملAsymmetric hydrogenation of quinazolinium salts catalysed by halide-bridged dinuclear iridium complexes bearing chiral diphosphine ligands.
Asymmetric hydrogenation of quinazolinium salts was catalysed by halogen-bridged dinuclear iridium complexes bearing chiral diphosphine ligands, yielding tetrahydroquinazoline and 3,4-dihydroquinazoline with high enantioselectivity. A derivative of chiral dihydroquinazoline was used as a chiral NHC ligand.
متن کاملAcetato-bridged dinuclear lanthanide complexes with single molecule magnet behaviour for the Dy2 species.
Five dinuclear lanthanide complexes with formula [Ln2L2(OAc)4(MeOH)a(H2O)b] · cMeOH · dH2O (a = 2, b = 0, c = 2, d = 0, Ln = Sm (1), Gd (2), Dy (3); a = 0, b = 2, c = 4, d = 2, Ln = Tm (4)) and [Yb2L2(OAc)4(MeOH)2]·[Yb2L2(OAc)4(H2O)2] · 2H2O (5) (HL = (E)-N'-(2-hydroxybenzylidene)-2-mercaptonicotinohydrazide), have been synthesized and their crystal structures and magnetic properties are report...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2017
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c7dt02728a